新疆石油天然气 ›› 2023, Vol. 19 ›› Issue (1): 89-94.DOI: 10.12388/j.issn.1673-2677.2023.01.013

• 油气开发 • 上一篇    

纳米微乳液驱油体系的构建及性能评价#br#

  

  1. 1.西南石油大学化学化工学院,四川成都 610500; 2.中国石油新疆油田分公司工程技术研究院(监理公司),新疆克拉玛依 834000
  • 出版日期:2023-03-06 发布日期:2023-03-06
  • 作者简介:郑存川(1987-),2017年毕业于西南石油大学应用化学专业,讲师,目前从事油田化学品工作液研究。(Tel)18428346930(E-mail)zcc870317@163.com
  • 基金资助:

    四川省重点研发项目“绿色环保热固性低密度压裂支撑剂研制及连续化生产关键技术”(2021YFG0112)

Construction and Performance Evaluation of Nano Microemulsion Oil Displacement System#br#

  1. 1. College of Chemistry and Chemical Engineering,Southwest Petroleum University,Chengdu 610500,Sichuan,China;

    2. Research Institute of Engineering Technology,PetroChina Xinjiang Oilfield Company,Karamay 834000,Xinjiang,China 

  • Online:2023-03-06 Published:2023-03-06

摘要:

微乳液驱油是一种有效的提高采收率技术。由十二烷基甜菜碱、异丙醇和90~120石油醚等制备微乳液,采用拟三元相图法研究助表面活性剂与表面活性剂比值Km对微乳液的影响,结果表明:随着Km值的增大,形成微乳区的面积先增大后减小,当Km=2时具有最大面积。通过微乳液稀释法制备了纳米微乳液驱油剂,采用激光散射系统和旋转滴界面张力仪分别测定其粒径分布和界面张力,结果表明:浓度为0.25%的平均粒径为149.0 nm;浓度为0.3%时具有最低界面张力为1.780 44 mN/m。实验室评价了纳米微乳液驱油剂的性能,结果表明:在不同温度下均具有良好的分散稳定性;浓度为0.5%时具有最大起泡高度为140 mm;浓度为0.3%时有最大乳化效率为55.0%;浓度为0.2%时具有最大洗油效率为88.39%;浓度为0.3%时总驱油采收率为86.78%

关键词:

纳米微乳液, 驱油剂, 三元相图, 助表面活性剂, 表面活性剂

Abstract:

Microemulsion flooding is an effective technology to improve oil recovery. Microemulsions were prepared using dodecyl betaine,isopropanol and 90 ~ 120 petroleum ether. The impact of Km,the ratio of cosurfactant to surfactant,on microemulsion was studied using the pseudo-ternary phase diagram method. The results show that with the increase of Km,the area of microemulsion formed increased first and then decreased,and reached the maximum when Km = 2. The nano-microemulsion oil displacement agent was prepared using the microemulsion dilution method. The particle size distribution and interfacial tension were measured by laser scattering system and spinning drop interface tensiometer,respectively. The results show that the average particle size is 149.0 nm when the concentration is 0.25 %,and the minimum interfacial tension is 1.780 44 mN/m when the concentration is 0.3 %. The properties of the nano microemulsion oil displacement agent were evaluated in the laboratory. The results show that it had good dispersion stability at different temperatures. The maximum foam height is 140 mm when the concentration is 0.5%;the maximum emulsification efficiency is 55.0% when the concentration is 0.3%;the maximum oil displacement efficiency is 88.39% when the concentration is 0.2%;when the concentration is 0.3%,the total oil recovery factor is 86.78%.

Key words:

"> nano microemulsion, oil displacement agent, ternary phase diagram, cosurfactant, surfactant