Xinjiang Oil & Gas ›› 2023, Vol. 19 ›› Issue (3): 38-41.DOI: 10.12388/j.issn.1673-2677.2023.03.006

• OIL AND GAS DEVELOPMENT • Previous Articles     Next Articles

Development and Evaluation of Block Silicone Oil Anti-Water Blocking Agent

  

  1. School of Petroleum Engineering,China University of Petroleum(East China),Qingdao 266580,Shandong,China
  • Online:2023-09-10 Published:2023-09-10

新型嵌段硅油防水锁剂的研制与评价

  

  1. 中国石油大学(华东)石油工程学院,山东青岛 266580
  • 作者简介:金家锋(1987-),2017年毕业于中国石油大学(华东)油气田开发工程专业,博士,副教授,主要从事油气藏保护理论与技术研究。(Tel)15621455297(E-mail)jinjf@upc. edu. cn
  • 基金资助:

    1.国家自然科学基金青年项目“宽光谱响应碳纳米管海绵去除废弃水基钻井液中重金属和有机物的协同机制研究”(52004316);

    2.中国石油天然气股份有限公司科学研究与技术开发项目“煤系地层‘三气合采’立体开发技术研究”(2021DJ2304)。

Abstract:

To prevent the water block damage induced by any extraneous fluid's invasion during drilling and completion operations in low-permeability gas reservoirs,a high-performance anti-water blocking agent(FWB),which is composed of hydrogen-rich block silicone oil and some additives such as organosilicon surfactant and deformer,was developed for low-permeability gas reservoirs. The infrared spectroscopy was used to characterize the molecular structure of the block silicone oil,and a series of tests,which include surface tension test,contact angle test,core imbibition test,permeability recovery ratio test,and drilling fluid compatibility test,were conducted to comprehensively evaluate the performance of this anti-water blocking agent. The test results show that,at the mass concentration of 1%,it can dramatically reduce the surface tension of the aqueous phase to 22.28 mN/m,increase the contact angle of the aqueous phase from 29° to 120°,decrease the core imbibition amount by 69.2%,and improve the permeability recovery ratio to 89.3%,and that it has good compatibility with drilling fluids. This anti-water blocking agent can significantly reduce the water block damage during drilling and completion operations and provide effective protection for low-permeability oil and gas reservoirs. 

Key words:

low-permeability gas reservoir, anti-water blocking agent, block silicone oil, permeability recovery ratio, contact angle, reservoir protection

摘要: 针对低渗气藏钻完井过程中外来流体侵入引发的水锁损害问题,以高含氢嵌段硅油为主剂,复配有机硅表面活性剂、消泡剂等助剂,制备了一种适用于低渗气藏的高性能防水锁剂FWB。采用红外光谱对嵌段硅油的分子结构进行了表征,并通过表面张力法、接触角法、岩心自吸法、渗透率恢复率实验和钻井液配伍性等实验综合评价了防水锁剂FWB的性能。实验结果表明,1%防水锁剂FWB可将水相表面张力大幅降低至22.28 mN/m,将水相接触角由29°提高至120°,岩心自吸水量的减少幅度达69.2%,且渗透率恢复率可提高至89.3%。该防水锁剂具有良好的钻井液配伍性。研制的防水锁剂FWB可以显著降低钻完井过程中的水锁损害程度,能有效保护低渗油气储层。

关键词:

低渗气藏, 防水锁剂, 嵌段硅油, 渗透率恢复率, 接触角, 储层保护

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